NON-AQUEOUS LIQUID-LIQUID-EXTRACTION - EXTRACTION OF ZINC FROM METHANOL-WATER SOLUTION OF CHLORIDE BY TRIOCTYLPHOSPHINE OXIDE IN DECALINE

被引：14

作者：

MATSUI, M

DOE, H

HIRADE, T

SHIGEMATSU, T

机构：

[1] Institute for Chemical Research, Kyoto University, Uji, Kyoto

来源：

ANALYTICAL LETTERS PART A-CHEMICAL ANALYSIS | 1979年 / 12卷 / 13期

关键词：

methanolic solution; nonaqueous solvent extraction; zinc;

D O I：

10.1080/00032717908067928

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The distribution of zinc was studied between the decaline phase having tri-n-octylphosphine oxide (TOPO) and the methanol-water phase (4:1 in molar ratio) having chloride ion, and the stability constants of zinc with chloride in the methanolic solution were calculated from the extraction experiments (K1=2.4×103, K2=1.9x102 at 298°K). Copyright © 1979 by Marcel Dekukr, Inc. All Rights Reserved.

引用

页码：1385 / 1397

页数：13

共 4 条

[1] THE CONDUCTANCE AT 25-DEGREES OF LITHIUM CHLORIDE, SODIUM AND POTASSIUM BROMIDES AND POTASSIUM IODIDE IN METHANOL, AND OF LITHIUM CHLORIDE, SODIUM BROMIDE AND POTASSIUM IODIDE IN WATER
JERVIS, RE
MUIR, DR
BUTLER, JP
GORDON, AR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (12) : 2855 - 2858
[2] MATSUI M, 1975, ANAL LETT, V8, P247
[3] Matsui M., 1974, B I CHEM RES KYOTO U, V52, P652
[4] ZINC CHLORIDE AND ZINC BROMIDE COMPLEXES .2. SOLVENT-EXTRACTION STUDIES WITH ZINC-65 AS TRACER
MORRIS, DFC
SHORT, EL
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1962, (JUL): : 2662 - &

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