A SIMPLE STEREOSELECTIVE SYNTHESIS OF GALBANOLENE, (3E,5Z)-1,3,5-UNDECATRIENE

被引：9

作者：

CHAPUIS, C

机构：

[1] Firmenich SA, Research Laboratories, CH-1211 Geneva 8

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 18期

关键词：

STEREOSELECTIVE; TRIENE; GALBANUM; DIYNE; MANNICH;

D O I：

10.1016/S0040-4039(00)92215-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new synthesis of (3E, 5Z)-1,3,5-undecatriene (2) is presented, based on a Mannich addition to 1,4 decadiyne, followed by Lindlar hydrogenation and Hydrogenation and Hofmann elimination. This "one pot" coupling of C-7 + C3 + C1 synthons affords 2 stereochemically pure.

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页码：2461 / 2464

页数：4

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