SUPRAMOLECULAR CONTROL OF MOLECULAR ELECTRONIC BEHAVIOR OF TCNQ- SALTS

被引：15

作者：

GROSSEL, MC

WESTON, SC

机构：

[1] Department of Chemistry, University, Highfield, Southampton

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 1992年 / 5卷 / 08期

关键词：

D O I：

10.1002/poc.610050816

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Crown ether complexation of 1:1 alkali metal TCNQ salts, MTCNQ (M = K, Rb, Tl) leads to structures containing isolated TCNQ dimers. These materials provide valuable models for investigating the spectroscopic and electronic behaviour of TCNQ-. dimer components which are key structural fragments of, for example, organic metals and semiconductors.

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页码：533 / 539

页数：7

相关论文

共 35 条

[1] 7,7,8,8-TETRACYANOQUINODIMETHANE AND ITS ELECTRICALLY CONDUCTING ANION-RADICAL DERIVATIVES [J].

ACKER, DS ;

HARDER, RJ ;

HERTLER, WR ;

MAHLER, W ;

MELBY, LR ;

BENSON, RE ;

MOCHEL, WE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (24) :6408-6409

[2] TRANSITION-METAL HYDROGEN ALKALI-METAL BONDS - SYNTHESES AND STRUCTURES OF W(PME3)3H5NA(15-CROWN-5), W(PME3)3H5K(18-CROWN-6), AND [W(PME3)3H5LI]4 [J].

BANDY, JA ;

BERRY, A ;

GREEN, MLH ;

PROUT, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (21) :1462-1464

[3] SYNTHESIS OF ANIONIC SANDWICH COMPOUNDS - [TI(ETA-C6H5R)2]- AND THE CRYSTAL-STRUCTURE OF [K(18-CROWN-6)(MU-H)MO(ETA-C5H5)2] [J].

BANDY, JA ;

BERRY, A ;

GREEN, MLH ;

PERUTZ, RN ;

PROUT, K ;

VERPEAUX, JN .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (11) :729-731

[4] SOLUTION DIMERIZATION OF TETRACYANOQUINODIMETHANE ION RADICAL [J].

BOYD, RH ;

PHILLIPS, WD .

JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (09) :2927-&

[5] ORGANIC METALS [J].

BRYCE, MR ;

MURPHY, LC .

NATURE, 1984, 309 (5964) :119-126

[6] INFLUENCE OF DIFFERENT DONOR ATOMS ON THE FORMATION OF 1-1-COMPLEXES AND 2-1-COMPLEXES OF 12-CROWN-4 AND 18-CROWN-6 ETHERS WITH AG+, TI-2+, BA-2+ AND PB-2+ [J].

BUSCHMANN, HJ .

THERMOCHIMICA ACTA, 1986, 107 :219-226

[7]

DOBLER M, 1974, ACTA CRYSTALLOGR B, V30, P2746, DOI 10.1107/S0567740874007953

[8] CRYSTAL-STRUCTURE ANALYSES OF 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE AND ITS COMPLEXES WITH ALKALI THIOCYANATES [J].

DUNITZ, JD ;

DOBLER, M ;

SEILER, P ;

PHIZACKERLEY, RP .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1974, 30 (NOV15) :2733-2738

[9] AC DIELECTRIC-SPECTROSCOPY OF OXONOL DYES - A VERSATILE PROBE FOR THE EXAMINATION OF CHARGE IN ORGANIC SEMICONDUCTORS [J].

GROSSEL, MC ;

EDWARDS, DJ ;

HILL, RM ;

DISSADO, LA .

JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (04) :423-431

[10]

GROSSEL MC, 1990, J CHEM SOC CHEM COMM, V5, P439

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