PREPARATION OF MONODISPERSE PEANUT-TYPE ALPHA-FE2O3 PARTICLES FROM CONDENSED FERRIC HYDROXIDE GEL

被引:165
作者
SUGIMOTO, T
KHAN, MM
MURAMATSU, A
机构
[1] Institute for Advanced Materials Processing, Tohoku University, Aobaku, Sendai, 980
关键词
FERRIC HYDROXIDE; GEL SOL METHOD; HEMATITE PARTICLES; MONODISPERSE COLLOID; MONODISPERSE PARTICLES;
D O I
10.1016/0927-7757(93)80285-M
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recently, it has been found that monodisperse pseudocubic hematite particles 1.65 mum in mean edge length can be obtained in large quantities of the order of the molality with a yield close to 100%, by adding 100 ml of 5.4 N NaOH to 100 ml of well-stirred 2.0 M FeCl3 and aging the resulting condensed gel of Fe(OH)3 for 8 days at 100-degrees-C. The method was provisionally referred to as the gel-sol method. As an application of this technique, when 90 ml of 6.0 N NaOH and 10 ml of sulfate or phosphate solution were added instead of 100 ml of 5.4 N NaOH, the pseudocubic particles turned into peanut-type particles via an ellipsoidal shape with increasing concentration of the additives.
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页码:167 / 169
页数:3
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