CHARGE-TRANSFER COMPLEXING IN POLYMER MIXTURES .3. REACTION OF ARYLIMINODIETHANOL POLYMERS WITH TETRACYANOETHYLENE

被引：17

作者：

SULZBERG, T

COTTER, RJ

机构：

[1] Union Carbide Corporation, Chemicals and Plastics, Bound Brook

来源：

MACROMOLECULES | 1969年 / 2卷 / 02期

关键词：

D O I：

10.1021/ma60008a008

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The reaction of tetracyanoethylene with the polyesters of several aryliminodiethanols was investigated. The products have the general formula [ROCH2CH2N(Ar)CH2CH2O]m-[ROCH2CH2N[ArC(CN)=C(CN)2]CH2CH2O]n When R is -COOC6H4C(<)C6H4OOC- Ar, the colors and visible absorption maxima are phenyl, red, 492 mµ; m-tolyl, red, 513 mµ; and 2,5-dimethoxyphenyl, purple, 535 and 395 mµ. The color of tricyanovinylated poly(tetrahydroquinoxaline-N,N′-diethanol bisphenol A carbonate) was green with absorption maxima of 590 and 435 mµ. Some insight into the mechanism of the reaction was made by studying the tricyanovinylation of polymers from p-anisyl- and 2-fluorenyliminodiethanols. © 1969, American Chemical Society. All rights reserved.

引用

页码：150 / &

共 7 条

[1] ISOLATION OF AN INTERMEDIATE IN TRICYANOVINYLATION OF NN-DI-METHYLANILINE [J].

FARRELL, PG ;

NEWTON, J ;

WHITE, RFM .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1967, (07) :637-&

[2]

HECKERT RE, 1956, Patent No. 2762810

[3] CHARGE-TRANSFER COMPLEXES - INTERACTIONS BETWEEN TETRACYANOETHYLENE AND AROMATIC AMINES [J].

ISAACS, NS .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1966, (11) :1053-&

[4]

KOSOWER EM, 1965, PROGR PHYS ORG CHEM, V3, P81, DOI DOI 10.1088/1748-9326/3/4/045008

[5] CYANOCARBON CHEMISTRY .6. TRICYANOVINYLAMINES [J].

MCKUSICK, BC ;

HECKERT, RE ;

CAIRNS, TL ;

COFFMAN, DD ;

MOWER, HF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (11) :2806-2815

[6] NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS .5. REACTION OF DIMETHYLANILINE WITH TETRACYANOETHYLENE - PI- AND SIGMA-COMPLEXES IN ELECTROPHILIC AROMATIC AND NUCLEOPHILIC VINYLIC SUBSTITUTIONS [J].

RAPPOPORT, Z .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (SEP) :4498-&

[7] CHARGE-TRANSFER COMPLEXING IN POLYMER MIXTURES .2. DONOR POLYMERS FROM ARYLIMINODIETHANOLS [J].

SULZBERG, T ;

COTTER, RJ .

MACROMOLECULES, 1969, 2 (02) :146-&

← 1 →