INTERACTION OF DISULFIDES WITH METHYLCOBALOXIME

被引：10

作者：

BROWN, KL

JINKERSON, D

机构：

[1] Department of Chemistry, The University of Texas at Arlington, Arlington

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 164卷 / 02期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0022-328X(00)86705-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Base-catalyzed hydrolysis of disulfides has been found to be accelerated by the presence of methyl(aquo)cobaloxime and to lead to the formation of methyl(thiolato)cobaloximes. This acceleration is prevented in the presence of a large excess of pyridine suggesting that disulfides associate to methylcobaloxime at the labile, axial ligand position. If such association occurs, it must be quite weak since no direct spectroscopic evidence for interaction of disulfides with methylcobaloxime in the absence of base could be obtained. © 1979.

引用

页码：203 / 209

页数：7

共 11 条

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