TEMPERATURE VARIATION OF HO ACIDITY FUNCTION IN AQUEOUS SULFURIC ACID SOLUTION

被引:341
作者
JOHNSON, CD
KATRITZK.AR
SHAPIRO, SA
机构
[1] School of Chemical Sciences, University of East Anglia, Norwich
关键词
D O I
10.1021/ja01052a021
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The variation of the H0 acidity function, as defined by primary nitroaniline indicators, with temperature, has been examined by measurement of the scale at 25, 40, 60, 80, and 90°. Empirical equations correlating H0 with temperature are deduced. The variation of pKa values with temperature and the application of the scale to other measurements on acidity scales and acid-catalyzed reactions, at elevated temperatures, are discussed. © 1969, American Chemical Society. All rights reserved.
引用
收藏
页码:6654 / &
相关论文
共 30 条