METAL-NITROXYL INTERACTIONS .12. NITROXYL SPIN PROBES IN THE PRESENCE OF TRIS(OXALATO)CHROMATE(III)

被引：30

作者：

YAGER, TD

EATON, GR

EATON, SS

机构：

[1] UNIV DENVER,DEPT CHEM,DENVER,CO 80208

[2] UNIV COLORADO,DEPT CHEM,DENVER,CO 80202

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 03期

关键词：

D O I：

10.1021/ic50193a039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cr(ox)33- is more effective than the commonly used Fe(CN)63- in broadening the EPR spectra of nitroxyl spin probes. The extent of broadening of the EPR spectrum of 4-amino-2, 2, 6, 6-tetramethylpiperidinyl-1-oxy by Cr(ox)33- depends on pH, the nature of the buffer, and the concentration of the nitroxyl as well as on the identity and concentration of the metal species. © 1979, American Chemical Society. All rights reserved.

引用

页码：725 / 727

页数：3

共 9 条

[1]

Bailar J. C., 1939, INORG SYNTH, V1, P35

[2] METAL-NITROXYL INTERACTIONS .5. INTERACTION OF SPIN LABELS WITH TRANSITION-METALS [J].