Isotope effect in the H-2-NMR-spectra of partly deuterated hydrates

被引：8

作者：

Pedersen, B. ^{[1
]}

Haland, K. ^{[1
]}

机构：

[1] Sentralinst Ind Forskning, Oslo 3, Norway

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 01期

关键词：

D O I：

10.1016/0009-2614(68)80150-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The quadrupole coupling constant. K, for the deuteren in the DHO-molecule is found to be about 1% larger than K in the D2O-molecule in partly deuterated potassium oxalate monohydrase. It increases slightly with the temperature, and this increase is explained qualitatively as being due to the stretching of the hydrogen bond.

引用

页码：61 / 64

页数：4

共 13 条

[1] GITTERPARAMETER VON EIS I BEI TIEFEN TEMPERATUREN [J].