REACTION OF PENTADIENYLIRON TRICARBONYL CATIONS WITH HYDRIDE DONORS

被引：33

作者：

BAYOUD, RS

BIEHL, ER

REEVES, PC

机构：

[1] Department of Chemistry, Southern Methodist University, Dallas

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 174卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)85595-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of pentadienyliron tricarbonyl cations has been prepared and reacted with the hydride ion donors sodium borohydride, sodium cyanoborohydride, and lithium triethylborohydride in order to determine steric and electronic effects in these reduction reactions. Sodium cyanoborohydride yields products of retained configuration whereas lithium triethylborohydride yields dieneiron tricarbonyl compounds of inverted configuration. Kinetic and thermodynamic considerations are used to account for these results. © 1979.

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页码：297 / 303

页数：7

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