OPTICAL-ACTIVITY MEASUREMENTS IN SOLIDS .5. OPTICAL-ROTATION OF NATURAL POLYMERS

被引：10

作者：

BARTUS, J

VOGL, O

机构：

[1] Polytechnic University, Six Metrotech Center, Brooklyn, New York

来源：

POLYMER INTERNATIONAL | 1994年 / 33卷 / 01期

关键词：

OPTICAL ACTIVITY; SOLID-STATE MEASUREMENTS; NATURAL POLYMERS; SUSPENSION; BIREFRINGENCE; ISOREFRACTIVE MEDIA;

D O I：

10.1002/pi.1994.210330104

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The optical activity of ten natural-type polymers [poly(alpha-aminoacids), polysaccharides, proteins and nucleic acids] was measured in solution, as solid powders in suspension, and where possible in the form of films. In some cases the specific rotation of powder samples showed significant differences to the values obtained from solution measurements. The discrepancies seem to reflect the arrangements of polymer chains in supermolecular assemblies in the polymer solid state.

引用

页码：25 / 36

页数：12

共 33 条

[1] CRYSTAL CHIRALITY AND OPTICAL-ROTATION SENSE IN ISOMORPHOUS NACLO3 AND NABRO3 [J].