FLOW-INJECTION CHEMILUMINOMETRIC DETERMINATION OF EPINEPHRINE, NOREPINEPHRINE, DOPAMINE AND L-DOPA

被引：179

作者：

DEFTEREOS, NT ^{[1
]}

CALOKERINOS, AC ^{[1
]}

EFSTATHIOU, CE ^{[1
]}

机构：

[1] UNIV ATHENS,ANALYT CHEM LAB,GR-15771 ATHENS,GREECE

来源：

ANALYST | 1993年 / 118卷 / 06期

关键词：

CHEMILUMINESCENCE; FLOW INJECTION; CONTINUOUS FLOW; EPINEPHRINE; CATECHOLAMINES;

D O I：

10.1039/an9931800627

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A method is proposed for the determination of 0.0500-1.00 mug ml-1 of epinephrine and L-dopa and 0.100-1.00 mug ml-1 of norepinephrine and dopamine by their chemiluminogenic oxidation with potassium permanganate in acidic medium, in the presence of formaldehyde, which greatly improves the sensitivity. Flow injection allows the measurement of 80 solutions per hour. The method was also optimized for a continuous-flow system. Comparative results from numerous organic compounds proved the necessity for electron-donating groups on the benzene ring for sensitive chemiluminescent characteristics.

引用

页码：627 / 632

页数：6

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