SYNTHESIS OF NOR-AMBREINOLIDE FROM (+)-CIS-ABIENOL

被引：16

作者：

BARRERO, AF

SANCHEZ, JF

ALVAREZMANZANEDA, EJ

ALTAREJOS, J

MUNOZ, M

HAIDOUR, A

机构：

[1] Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Granada

来源：

TETRAHEDRON | 1994年 / 50卷 / 22期

关键词：

D O I：

10.1016/S0040-4020(01)89693-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of nor-ambreinolide (2) from cis-abienol (1) was carried out by direct treatment with OsO4-NaIO4 or RuO4-NaIO4. The oxymercuriation-demercuriation of I led to a mixture of 8,12-epoxylabdanes (5-17) which was also converted into nor-ambreinolide by treatment with RuO4-NaIO4. The formation pathways of such epoxy derivatives are discussed.

引用

页码：6653 / 6662

页数：10

共 29 条

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