PREPARATION AND REACTIVITY OF PLATINUMCYCLOBUTADIENE COMPLEXES [PTCL2(C(4)R(4))L]

被引：7

作者：

GERISCH, M

STEINBORN, D

机构：

[1] Institut F. Anorg. Chemie, Martin-Luther-Universität Halle-Wittenberg, Halle, D‐06120

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 08期

关键词：

PLATINUM COMPLEXES; CYCLOBUTADIENE COMPLEXES;

D O I：

10.1002/zaac.19956210824

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

H[PtCl3(C4H8)], prepared by reduction of H-2[PtCl6] with n-butanol reacts with 2-pentyne to give equal amounts of the regioisomers [PtCl2(C(4)Et(2)Me(2))] (3a, 3b). An equimolar mixture of 2-butyne/3-hexyne reacts under the same conditions to give [PtCl2(C(4)Me(4))] (1), [PtCl2(C(4)Et(4))] (2) and PtCl2(C(4)Et(2)Me(2))] (3 a) in a molar ratio 1:1.3:6.6. 1 and 2 react with ligands L (L = py a, p-tol b, PPh(3) c, AsPh(3) d, SbPh(3) e) to give complexes of the type [PtCl2(C(4)R(4))L]. The complexes were characterized by microanalysis as well as by i.r., H-1- and C-13-n.m.r. spectroscopy.

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页码：1426 / 1430

页数：5

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