KINETIC ISOTOPE EFFECT IN FORMATION OF ANTHRAQUINONE

被引：2

作者：

NOYCE, DS

KITTLE, PA

BANITT, EH

机构：

[1] Department of Chemistry, University of California, Berkeley

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1968年 / 33卷 / 04期

关键词：

D O I：

10.1021/jo01268a040

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rate of formation of anthraquinone from 2-(2'-deuteriobenzoyl)benzoic acid is less than the rate for the protium analog, KH/KD varying from 1.28 in 97% sulfuric acid to 1.20 in 104% sulfuric acid. The product anthraquinone retains from 56 to 62% of one deuterium. The mechanistic implications of these results are discussed. © 1968, American Chemical Society. All rights reserved.

引用

页码：1500 / &

共 29 条

[1]

BATTS BD, 1964, J CHEM SOC, P4284

[2]

BERLINER E, 1960, CHEM IND-LONDON, P1444

[3] NITRATION IN SULPHURIC ACID .9. THE RATES OF NITRATION OF NITROBENZENE AND PENTADEUTERONITROBENZENE [J].