TRANS-BIS(TETRACARBONYLCOBALTATO)BIS(PYRIDINE)PLATINUM(2) AND TRANS-BIS(PENTACARBONYLMANGANATO)BIS(PYRIDINE)- PLATINUM(2)

被引：35

作者：

PEARSON, RG

DEHAND, J

机构：

[1] Department of Chemistry, Northwestern University, Evanston

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 16卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)89774-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and properties of trans-PtPy2[Co(CO)4]2 and trans- PtPy2[Mn(CO)5]2 are described. The metal carbonyl anion Co(CO)-4 is studied as a leaving group by measuring the rate of the cleavage reaction PtPy2[Co(CO)4]2+2 Y ⇌ [PtPy2Y2]2+ + 2 Co(CO)-4 Y = (C6H5)3P, (n-C4H9)3P in tetrahydrofuran. The products of these reactions are also described. © 1969.

引用

页码：485 / &

共 20 条

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