Covalency effects from mossbauer experiments. on the hydrates of fecl(2)

被引：35

作者：

Hazony, Y. ^{[1
]}

Axtmann, R. C. ^{[1
]}

Hurley, J. W., Jr. ^{[1
]}

机构：

[1] Princeton Univ, Dept Chem Engn, Princeton, NJ 08540 USA

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 07期

关键词：

D O I：

10.1016/0009-2614(65)80005-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The results of Mossbauer studies on the hydrates of ferrous chloride show a nearly linear correlation between the quadrupole splitting and isomer shift. The correlation is discussed in terms of central field and symmetry restricted covalency. A comparative analysis of the present correlation and previous results on anhydrous ferrous halides reveals information about the relative importance of sigma and pi bonds in these compounds.

引用

页码：440 / 444

页数：5

共 27 条

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