FACILE SEPARATIONS OF ENANTIOMERS OF CHIRAL ORGANOMETALLIC COMPOUNDS WITH A BAKERBOND CHIRALCEL HPLC COLUMN

被引：32

作者：

RAMSDEN, JA ^{[1
]}

GARNER, CM ^{[1
]}

GLADYSZ, JA ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 05期

关键词：

D O I：

10.1021/om00051a066

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiomers of 22 compounds of the formula (eta-5-C5R5)M(L)(PAr3)(X) (M/L = Re/NO, Fe/CO) are separated under the title conditions (hexane/2-propanol). In each case, theoretical plate numbers, capacity factors, separation factors, and resolution are determined. Trends in these data and compounds for which enantiomers are not resolved are discussed.

引用

页码：1631 / 1633

页数：3

共 17 条

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