NOVEL 2-FOLD-MACROCYCLE-SUBSTITUTED PHTHALOCYANINES

被引：81

作者：

KOCAK, M

OKUR, AI

BEKAROGLU, O

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 03期

关键词：

D O I：

10.1039/dt9940000323

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New metallophthalocyanines (M = Cu or Ni) substituted in peripheral positions with four 14-membered tetraaza macrocycles each attached to a 15-membered crown ether have been prepared in a multi-step reaction sequence. The N-tosylated derivatives are extensively soluble in apolar solvents and form adducts with alkali-metal cations. Detosylation of the macrocyclic aza groups provides donor sites for binding transition-metal ions (e.g. Ni-II) which leads to pentanuclear water-soluble complexes.

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页码：323 / 326

页数：4

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