AN UNUSUAL RHODIUM IODOCARBONYL SYSTEM

被引：14

作者：

KINGSTON, JV

SCOLLARY, GR

机构：

[1] Department of Chemistry, La Trobe University, Melbourne

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 08期

关键词：

D O I：

10.1016/0022-1902(69)80588-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Interaction of tertiary phosphines, arsines and stibines with iodocarbonylrhodium solutions yields the complexes, [Rh(CO)L2I] and [Rh(CO)L2I3, whereas with pyridine and aniline, anions of the type [Rh(CO)LI4]- are the only products obtained. The isolation of geometrical isomers of [Rh(CO)2I4]- from the same iodocarbonyl solution is discussed. [Rh(CO)2I4]- from the same iodocarbonyl solution is discussed. © 1969.

引用

页码：2557 / &

共 8 条

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