A NEW ROUTE TO EARLY-LATE HETEROBIMETALLIC MU-ALKYLIDENE COMPLEXES

被引:5
作者
CASEY, CP
ASKHAM, FR
PETROVICH, LM
机构
[1] Department of Chemistry, University of Wisconsin, Madison
基金
美国国家科学基金会;
关键词
D O I
10.1016/0022-328X(90)87188-J
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of two equivalents of Cp2ZrHCl (1) with Cp(CO)2ReCHR (2, R = CH2CH2CMe3; 4, R = CH3) led to the formation of the heterobimetallic μ-alkylidene complexes Cp2Zr(μ-CHR)(μ,η1,η2-CO)Re(CO)Cp (3, R = CH2CH2CMe3; 5, R = CH3). © 1990.
引用
收藏
页码:C31 / C35
页数:5
相关论文
共 13 条
[1]   A NEW SYNTHESIS OF RHENIUM CARBENE COMPLEXES FROM THE REACTION OF CP(CO)2REH- WITH CP2ZR(PI-2-COR)CL [J].
CASEY, CP ;
NAGASHIMA, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (06) :2352-2353
[2]  
CASEY CP, UNPUB J AM CHEM SOC
[3]  
CASEY CP, 1988, 4THE EUR S IN CHEM F
[4]   PREPARATION OF HETERODINUCLEAR COMPLEXES CONTAINING MU-ALKYLIDENE LIGANDS [J].
DAVIS, JH ;
LUKEHART, CM ;
SACKSTEDER, LA .
ORGANOMETALLICS, 1987, 6 (01) :50-55
[5]   CHEMISTRY OF DI-METAL AND TRI-METAL COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .18. SYNTHESIS OF THE COMPLEXES [MW(MU-CC6H4ME-4)(MU-(SIGMA-ETA-2-CO))(CO)(ETA-C5H5)3](M= TI OR ZR) AND THE CRYSTAL-STRUCTURE OF THE TITANIUM TUNGSTEN COMPOUND [J].
DAWKINS, GM ;
GREEN, M ;
MEAD, KA ;
SALAUN, JY ;
STONE, FGA ;
WOODWARD, P .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (03) :527-530
[6]   HYDROZIRCONATION ORGANIC SYNTHESIS VIA ORGANOZIRCONIUM INTERMEDIATES - SYNTHESIS AND REARRANGEMENT OF ALKYLZIRCONIUM(IV) COMPLEXES AND THEIR REACTION WITH ELECTROPHILES [J].
HART, DW ;
SCHWARTZ, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (26) :8115-8116
[7]   BUILDING BRIDGES BETWEEN INORGANIC AND ORGANIC-CHEMISTRY (NOBEL LECTURE) [J].
HOFFMANN, R .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1982, 21 (10) :711-724
[8]  
HORWITZ CP, 1984, ADV ORGANOMET CHEM, V23, P219
[9]   SYNTHESIS AND REACTIONS OF DICARBONYL(ETA-CYCLOPENTADIENYL)DIHYDRIDORHENIUM(III) [J].
HOYANO, JK ;
GRAHAM, WAG .
ORGANOMETALLICS, 1982, 1 (06) :783-787
[10]   RAPID, REVERSIBLE INTRAMOLECULAR C-H OXIDATIVE ADDITION AND HYDROGEN-EXCHANGE IN A HETERODINUCLEAR EARLY LATE TRANSITION-METAL COMPLEX [J].
JACOBSEN, EN ;
GOLDBERG, KI ;
BERGMAN, RG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (11) :3706-3707