IN5S4 = SNIN4S4 - A REVISION

被引：16

作者：

DEISEROTH, HJ

PFEIFER, H

机构：

[1] Universität-GH-Siegen., W-5900 Siegen, Fachbereich 8

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1991年 / 196卷 / 1-4期

关键词：

TIN INDIUM SULFIDE; CRYSTAL STRUCTURE; ZINTL ION;

D O I：

10.1524/zkri.1991.196.1-4.197

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

By X-ray diffraction and microprobe analysis combined with variations of the chemical preparation it could be shown that "In5S4" described as a binary sulfide in the literature is in fact a ternary compound with the composition SnIn4S4. It contains tetrahedral [SnIn4]8+ cations centered by a tin atom. This cluster cation does no longer contradict to Zintl's valency rules as the formerly stated [In5]8+ in "In5S4" did. There is no evidence for the existence of In5S4.

引用

页码：197 / 205

页数：9

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