Silica-Supported Spinel LiMn2O4 from Microemulsion-Derived Multicomponent Gels

被引：4

作者：

Ammundsen, Brett ^{[1
]}

Burns, Gary R. ^{[1
]}

Amran, Ali ^{[2
]}

Friberg, Stig E. ^{[2
]}

机构：

[1] Victoria Univ Wellington, Dept Chem, Wellington, New Zealand

[2] Clarkson Univ, Ctr Adv Mat Proc, Potsdam, NY 13699 USA

来源：

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY | 1994年 / 2卷 / 1-3期

关键词：

lithium manganate; spinel ion exchange; microemulsion;

D O I：

10.1007/BF00486267

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A preparative technique based on the gelation of a microemulsion has provided a means of homogeneously dispersing high concentrations of metal oxide precursor salts through silica gel. The microstructures and compositions of gels containing combinations of lithium and manganese nitrate, and of the multiphase materials obtained by firing to a range of temperatures up to 1000 degrees C, have been established. Formation of the mixed metal oxide spinel phase LiMn2O4 within a silica support has been obtained for systems comprising from 10 to 30 wt% metal nitrate by heating to temperatures between 500 and 700 degrees C.

引用

页码：341 / 346

页数：6

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