MOSSBAUER EFFECT OF 129I IN PYRIDINE COMPLEXES OF IODINE MONOHALIDES

被引：20

作者：

WYNTER, CI

HILL, J

BLEDSOE, W

SHENOY, GK

RUBY, SL

机构：

[1] A and T State University of North Carolina, Greensboro, NC

[2] Argonne National Laboratory, Argonne, IL

[3] School of Chemistry, Rutgers Uni-versity, New Brunswick

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 09期

关键词：

D O I：

10.1063/1.1671642

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The values of isomer shift and quadrupole interaction at the 129I nucleus in IBr and ICI complexes with cyclic nitrogen bases have been measured. These have been used to estimate σ and π bondings in these complexes. All these complexes exhibit a linear N-I-X (X=C1, Br) linkage. Although the bromine complexes show a systematic dependence of the isomer shift on the basicity of the complexing cyclic amines, no such trend is observed in chlorine complexes.

引用

页码：3872 / &

共 12 条

[1] 2 INDEPENDENT DETERMINATIONS OF CRYSTAL AND MOLECULAR STRUCTURE OF IODINE MONOCHLORIDE COMPLEX OF PENTAMETHYLENETETRAZOLE [J].