METABOLISM OF HYDROXYSIMAZINE BY CORN PLANTS

被引:11
作者
MONTGOMERY, ML
BOTSFORD, DL
FREED, VH
机构
[1] Department of Agricultural Chemistry, Oregon State University, Corvallis, Ore.
关键词
D O I
10.1021/jf60166a033
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
The metabolic products of hydroxysimazine in corn plants were studied. The primary metabolite was a result of dealkylation, yielding 2-hydroxy-4-amino-6-ethylamino-s-triazine. This nonvolatile product was determined by gas chromatography as its trimethylsilyl derivative. Paper chromatography of the other metabolites indicated a second dealkylation occurs, giving rise to ammeline. In addition, there is also a product which corresponds to ammelide. Cotton, which is able to dealkylate diuron, is also capable of dealkylating hydroxysimazine. The dealkylation of herbicides appears to be an important pathway of detoxification. © 1969, American Chemical Society. All rights reserved.
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页码:1241 / +
页数:1
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