EXAMPLE OF THE EQUILIBRIUM ETHYLENEHYDRIDOMETAL REVERSIBLE ETHYLMETAL COMPLEX

被引：63

作者：

WERNER, H

FESER, R

机构：

[1] Institut Für Anorganische Chemie Der Universität, Würzburg

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 02期

关键词：

D O I：

10.1002/anie.197901571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An understanding of the processes involved in the insertion of olefins into MH bonds is important for many catalytic processes. Equilibrium between an ethylenehydrido‐metal 1 and an ethyl‐metal complex 2 in solution has been demonstrated for the first time. (Formula Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：157 / 158

页数：2

共 6 条

[1] ALKYL, ALKYNYL, AND OLEFIN COMPLEXES OF "BIS(PI-CYCLOPENTADIENYL)-MOLYBDENUM OR BIS(PI-CYCLOPENTADIENYL)-MOLYB-TUNGSTEN - REVERSIBLE METAL-TO-RING TRANSFER OF AN ETHYL GROUP
BENFIELD, FW
GREEN, MLH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (12): : 1324 - 1331
[2] SOME INSERTION REACTIONS OF PLATINUM HYDRIDO-COMPLEXES WITH OLEFINS - HYDROLYSIS OF PLATINUM-CARBON SIGMA-BONDS
DEEMING, AJ
JOHNSON, BFG
LEWIS, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (17): : 1848 - 1852
[3] DEY K, J ORGANOMET CHEM
[4] REACTIVITY OF COORDINATED LIGANDS .13. ELECTROPHILIC SUBSTITUTION REACTIONS OF CYCLOHEXA-1,3-DIENE COMPLEXES OF RHODIUM(I) AND IRIDIUM(I)
JOHNSON, BFG
LEWIS, J
YARROW, DJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (19): : 2084 - &
[5] TEBBE FN, 1971, J AM CHEM SOC, V93, P3793
[6] WERNER H, CHEM BER

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