BENZENETELLURINIC MIXED ANHYDRIDES AS MILD OXIDIZING-AGENTS

被引：19

作者：

FUKUMOTO, T ^{[1
]}

MATSUKI, T ^{[1
]}

HU, NX ^{[1
]}

ASO, Y ^{[1
]}

OTSUBO, T ^{[1
]}

OGURA, F ^{[1
]}

机构：

[1] HIROSHIMA UNIV, FAC ENGN, DEPT APPL CHEM, HIROSHIMA 724, JAPAN

来源：

CHEMISTRY LETTERS | 1990年 / 12期

关键词：

D O I：

10.1246/cl.1990.2269

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three benzenetellurinic mixed anhydrides, i.e., benzenetellurinyl acetate, trifluoroacetate, and trifluoromethanesulfonate, have been found to be mild oxidizing agents for various substrates such as thiol, phosphine, acyloin, alpha-hydroxy ester, catechol, hydroquinone, thiourea, and thioamide. The reactions towards the last two substrates are highly chemoselective, depending on both the reagent and substrate.

引用

页码：2269 / 2272

页数：4

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