THE ELECTRIC-FIELD GRADIENT AT GD-NUCLEI IN INTERMETALLIC COMPOUNDS WITH CACU5 RELATED STRUCTURES

被引：19

作者：

BUSCHOW, KHJ ^{[1
]}

COEHOORN, R ^{[1
]}

MULDER, FM ^{[1
]}

THIEL, RC ^{[1
]}

机构：

[1] LEIDEN UNIV,KAMERLINGH ONNES LAB,2300 RA LEIDEN,NETHERLANDS

来源：

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS | 1993年 / 118卷 / 03期

关键词：

D O I：

10.1016/0304-8853(93)90437-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Gd-155 Mossbauer spectroscopy was used to measure the electric field gradient (EFG) at the Gd nucleus in GdT5 compounds (T = Co, Ni, Cu and Rh) and GdT3B2 compounds (T = Rh, Ru and Co). The crystal structure of these compounds is of the CaCu5 type. Using the results of self-consistent band structure calculations of the valence electron contributions to the EFG, it is shown that the main contribution, comes from the asphericity of the Gd 6p valence electron charge density.

引用

页码：347 / 351

页数：5

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