CR5+ LUMINESCENCE FROM CHROMIUM-DOPED SIO2 GLASS

被引：36

作者：

HERREN, M

NISHIUCHI, H

MORITA, M

机构：

[1] Department of Industrial Chemistry, Seikei University, Musashino-Shi

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 101卷 / 05期

关键词：

D O I：

10.1063/1.467430

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The room-temperature photoluminescence spectrum of SiO2 glass: 0.1% Cr prepared by sol-gel method is reported. It consists of a broad band centered at 14 900 cm(-1) with a width of 4200 cm(-1) and a lifetime in the mu S Order and is attributed to the d-d transition of Cr5+ ions (3d(1) electron configuration). Absorption and emission spectra give no evidence for the presence of Cr3+ Or Cr4+ ions.

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页码：4461 / 4462

页数：2

相关论文

共 14 条

[1] LUMINESCENCE OF EU3+ IONS DURING THERMAL DENSIFICATION OF SIO2 GEL [J].

CAMPOSTRINI, R ;

CARTURAN, G ;

FERRARI, M ;

MONTAGNA, M ;

PILLA, O .

JOURNAL OF MATERIALS RESEARCH, 1992, 7 (03) :745-753

[2]

COTTON FA, 1980, ADV INORG CHEM RAD, P730

[3] THEORY OF INTERCONFIGURATIONAL NONRADIATIVE-TRANSITIONS IN TRANSITION-METAL IONS IN SOLIDS AND APPLICATION TO THE TI3+AL2O3 SYSTEM [J].

GRINBERG, M ;

MANDELIS, A ;

FJELDSTED, K .

PHYSICAL REVIEW B, 1993, 48 (09) :5935-5944

[4] DISORDER AND NONRADIATIVE DECAY OF CR3+-DOPED GLASSES [J].

HENDERSON, B ;

YAMAGA, M ;

GAO, Y ;

ODONNELL, KP .

PHYSICAL REVIEW B, 1992, 46 (02) :652-661

[5] NEAR-INFRARED LUMINESCENCE PROPERTIES OF THE LASER MATERIAL CR-Y2SIO5 [J].

HOMMERICH, U ;

EILERS, H ;

JACOBSEN, SM ;

YEN, WM ;

JIA, W .

JOURNAL OF LUMINESCENCE, 1993, 55 (5-6) :293-301

[6] DISTRIBUTION OF LOW FIELD SITES OF CR(III) IN SILICATE GLASS FROM AN ANALYSIS OF THE BROAD 4T2 FLUORESCENCE BAND [J].

KOSCH, J ;

SEELERT, W ;

STRAUSS, E .

JOURNAL OF LUMINESCENCE, 1990, 45 (1-6) :105-107

[7] SPECTROSCOPIC CHARACTERIZATION OF V-4+-DOPED AL2O3 AND YA1O3 [J].

MEYN, JP ;

DANGER, T ;

PETERMANN, K ;

HUBER, G .

JOURNAL OF LUMINESCENCE, 1993, 55 (02) :55-62

[8]

Moulton P., 1982, OPT NEWS, V8, P9, DOI DOI 10.1364/ON.8.6.000009

[9] AN INFRARED BAND-EMITTER AT THE OPTICAL-COMMUNICATION WAVELENGTHS - CR-ACTIVATED ZN2SIO4 [J].

PAPPALARDO, RG ;

MINISCALCO, WJ ;

PETERS, TE ;

LEE, K .

JOURNAL OF LUMINESCENCE, 1993, 55 (02) :87-93

[10] LASER ACTION IN CHROMIUM-ACTIVATED FORSTERITE FOR NEAR-INFRARED EXCITATION - IS CR-4+ THE LASING ION [J].

PETRICEVIC, V ;

GAYEN, SK ;

ALFANO, RR .

APPLIED PHYSICS LETTERS, 1988, 53 (26) :2590-2592