ANODIC FLUORINATION OF AROMATIC THIOETHERS SUBSTITUTED BY STRONGLY ELECTRON-WITHDRAWING GROUPS

被引：8

作者：

BAROUX, P ^{[1
]}

TARDIVEL, R ^{[1
]}

SIMONET, J ^{[1
]}

机构：

[1] UNIV RENNES 1,CNRS,ELECTROCHIM ORGAN LAB,F-35042 RENNES,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 22期

关键词：

D O I：

10.1016/0040-4039(95)00654-U

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Arylalkylthioethers (aryl substituted by efficiently withdrawing groups) were anodically oxidized in the presence of Et(3)N, 3HF. Monofluorinations occuring often in good yield were found to be regiospecific onto the alpha-carbon of the aliphatic chain branched to the sulfur atom.

引用

页码：3851 / 3852

页数：2

共 8 条

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[6] ELECTROCHEMICAL MONOFLUORINATION AND DIFLUORINATION OF BENZYL-GROUPS
LAURENT, E
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[7] WELCH JT, 1990, FLUORINE BIOORGANICC
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[J]. CHEMICAL REVIEWS, 1992, 92 (04) : 505 - 519

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