THE REMARKABLE EFFECT OF E/Z ISOMERS ON THE CATALYTIC ASYMMETRIC HYDROGENATION OF OXIMES

被引：38

作者：

CHAN, ASC

CHEN, CC

LIN, CW

LIN, YC

CHENG, MC

PENG, SM

机构：

[1] NATL CHUNGHSING UNIV,DEPT CHEM,TAICHUNG 40227,TAIWAN

[2] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10764,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 17期

关键词：

D O I：

10.1039/c39950001767

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The E and Z isomers of 1-acetonaphthone oxime are isolated, characterized, and subjected to catalytic asymmetric hydrogenation; the chiral products from the asymmetric hydrogenation reflect the effect of the E and Z isomers on the enantioselectivity of the reaction.

引用

页码：1767 / 1768

页数：2

共 9 条

[1]

ALPER H, 1992, TETRAHEDRON-ASYMMETR, V3, P1283

[2]

[Anonymous], 1994, ASYMMETRIC CATALYSIS

[3]

BRUNNER H, 1988, TOP STEREOCHEM, V18, P129

[4] ENANTIOSELECTIVE HYDROGENATION OF THE C=N GROUP - A CATALYTIC ASYMMETRIC REDUCTIVE AMINATION PROCEDURE [J].