LICHENS AND FUNGI .6. DEHYDRATION REARRANGEMENTS OF 15-HYDROXYHOPANES

被引:29
作者
CORBETT, RE
SMITH, RAJ
机构
[1] Chemistry Department, University of Otago, Dunedin
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 01期
关键词
D O I
10.1039/j39690000044
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Dehydration of 15α-hydroxyhopane and of the 21αH-epimer gives the corresponding 13(14→15)abeo-hop-14(27)-enes together with alkenes which result from migration of the C-14 methyl group. Dehydration of 15β-hydroxyhopane and of the 21α-H-epimer is also accompanied by migration of the C-14 methyl group.
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页码:44 / &
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