HYDROGEN-CARBON-13 SPIN-SPIN COUPLING IN TRANSITION METAL HYDRIDE COMPLEXES

被引：39

作者：

WHITESIDES, GM

MAGLIO, G

机构：

[1] Department of Chemistry, Massachusetts Institute of Technology, Cambridge

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 18期

关键词：

D O I：

10.1021/ja01046a006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Analysis of the proton nmr spectra of K3[HIr(CN)5] (1), K3[HRh(CN)5] (2), trans-[HPtCN(P(C2H5)3)2] (4), HMn(CO)5 (5), cis-HMn(CO)4P(C2H5)3 (6), Na[HW2(CO)10] (7), and Na[HMo2(CO)10] (8) either naturally abundant or isotopically enriched in 13CN or 13CO has yielded values of 1H-M-13C spin-spin coupling constants for representative transition metal carbonyl and cyano hydrides. The utility of these coupling constants in structural investigations of hydride complexes of the transition metals is discussed briefly, with particular reference to compounds 2, 5, and 6. © 1969, American Chemical Society. All rights reserved.

引用

页码：4980 / +

页数：1

共 66 条

[1] ELECTRONIC STRUCTURES OF HEXACYANOMETALATE COMPLEXES [J].

ALEXANDER, JJ ;

GRAY, HB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (16) :4260-+

[2] SOME ASPECTS OF NUCLEAR MAGNETIC RESONANCE SPECTRA OF COMPOUNDS CONTAINING C-METHYL GROUPS [J].

ANET, FA .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1961, 39 (11) :2262-&

[3] REACTIONS OF GASES IN SOLUTION .1. PRODUCTS OF REACTION OF HYDROGEN WITH COBALT(2) CYANIDE COMPLEXES [J].

BANKS, RGS ;

PRATT, JM .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (04) :854-&

[4] METAL CARBONYLS .7. ACID-INDUCED EXCHANGE OF CARBON MONOXIDE WITH SOME INERT METAL CARBONYLS [J].

BASOLO, F ;

BRAULT, AT ;

POE, J .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (FEB) :676-&

[5] ELECTRONIC STRUCTURES OF METAL HEXACARBONYLS [J].

BEACH, NA ;

GRAY, HB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (21) :5713-&

[6] AN APPRAISAL OF VALENCE-BOND STRUCTURES AND HYBRIDIZATION IN COMPOUNDS OF THE 1ST-ROW ELEMENTS [J].

BENT, HA .

CHEMICAL REVIEWS, 1961, 61 (03) :275-311

[7] METAL CARBONYL CHEMISTRY .I. REACTIONS OF PHOSPHORUS-CONTAINING LIGANDS WITH HYDRIDOPENTACARBONYLMANGANESE [J].

BOOTH, BL ;

HASZELDI.RN .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (02) :157-&

[8] SPECTROSCOPIC STUDIES OF ISOTOPICALLY SUBSTITUTED METAL CARBONYLS .2. ASSIGNMENT OF CARBONYL STRETCHING ABSORPTIONS AND THEIR INTERACTION WITH METAL-HYDROGEN STRETCHING MODES IN PENTACARBONYL HYDRIDES [J].

BRATERMAN, PS ;

HARRILL, RW ;

KAESZ, HD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (12) :2851-+

[9] FORMATION OF AMMONIA BY INSERTION OF MOLECULAR NITROGEN INTO METAL-HYDRIDE BONDS .2. DI-MU-IMINO-BIS(DICYCLOPENTADIENYLTITANIUM(3) AS A PRODUCT OF REACTION BETWEEN DI-MU-HYDRIDO-BIS(DICYCLOPENTADIENYLTITANIUM(3) AND MOLECULAR NITROGEN [J].

BRINTZIN.H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (18) :4307-&

[10] FORMATION OF AMMONIA BY INSERTION OF MOLECULAR NITROGEN INTO METAL-HYDRIDE BONDS .I. FORMATION OF DIMERIC DICYCLOPENTADIENYLTITANIUM(3) HYDRIDE AS AN INTERMEDIATE IN VOLPIN-SHUR NITROGEN-FIXING SYSTEM [J].

BRINTZINGER, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (18) :4305-+

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