MODEL FOR ION-TRANSPORT IN BIPOLAR MEMBRANES

被引：75

作者：

MAFE, S ^{[1
]}

MANZANARES, JA ^{[1
]}

RAMIREZ, P ^{[1
]}

机构：

[1] UNIV CASTILLA LA MANCHA, DEPT FIS APLICADA, E-02071 ALBACETE, SPAIN

来源：

PHYSICAL REVIEW A | 1990年 / 42卷 / 10期

关键词：

D O I：

10.1103/PhysRevA.42.6245

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

A simple theory for multi-ionic transport, nonequilibrium water dissociation, and space-charge effects in bipolar membranes is developed on the basis of some of the concepts used in the solid-state n-p junction. Ion transport is described in terms of the Nernst-Planck flux equation and nonequilibrium water dissociation is accounted for by the Onsager theory of the second Wien effect. The model is expected to be of interest for biological and synthetic membranes, and can explain a number of observed effects. © 1990 The American Physical Society.

引用

页码：6245 / 6248

页数：4

共 20 条

[1] NON-EQUILIBRIUM EFFECTS DUE TO ION-TRANSPORT AT THE FORWARD BIASED INTERFACE BETWEEN AN ELECTROLYTE SOLUTION AND AN INFINITELY THICK ION-EXCHANGE MEMBRANE [J].

BASSIGNANA, IC ;

REISS, H .

JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (01) :136-149

[2] ION-TRANSPORT AND WATER DISSOCIATION IN BIPOLAR ION-EXCHANGE MEMBRANES [J].

BASSIGNANA, IC ;

REISS, H .

JOURNAL OF MEMBRANE SCIENCE, 1983, 15 (01) :27-41

[3] DEVELOPMENT OF BIPOLAR MEMBRANES [J].

BAUER, B ;

GERNER, FJ ;

STRATHMANN, H .

DESALINATION, 1988, 68 (2-3) :279-292

[4]

BRUMLEVE TR, 1978, J ELECTROANAL CHEM, V90, P1, DOI 10.1016/S0022-0728(78)80137-5

[5] KINETICS OF BULK AND INTERFACIAL IONIC MOTION - MICROSCOPIC BASES AND LIMITS FOR THE NERNST-PLANCK EQUATION APPLIED TO MEMBRANE SYSTEMS [J].

BUCK, RP .

JOURNAL OF MEMBRANE SCIENCE, 1984, 17 (01) :1-62

[6] A QUANTITATIVE ANALYSIS OF VOLTAGE-CURRENT RELATIONSHIPS OF FIXED CHARGE MEMBRANES AND ASSOCIATED PROPERTY OF PUNCH-THROUGH [J].

COSTER, HGL .

BIOPHYSICAL JOURNAL, 1965, 5 (05) :669-&

[7] MEMBRANE-POTENTIAL AND PERMEATION OF SALTS ACROSS BIPOLAR MEMBRANES [J].

HIGUCHI, A ;

NAKAGAWA, T .

JOURNAL OF MEMBRANE SCIENCE, 1987, 32 (2-3) :267-280

[8]

JONSSON G, UNPUB

[9]

Lakshminarayanaiah N., 1984, EQUATIONS MEMBRANE B

[10] SOME ELECTROCHEMICAL ASPECTS OF ION-EXCHANGE MEMBRANE JUNCTIONS [J].

LOVRECEK, B ;

SRB, V ;

KUNST, B .

ELECTROCHIMICA ACTA, 1967, 12 (07) :905-&

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