HIGH-TEMPERATURE LAMINATING RESINS BASED ON MALEIMIDO END-CAPPED PYROMELLITIMIDE

被引：19

作者：

MIKROYANNIDIS, JA ^{[1
]}

MELISSARIS, AP ^{[1
]}

机构：

[1] UNIV PATRAS,DEPT CHEM,CHEM TECHNOL LAB,GR-26001 PATRAS,GREECE

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1988年 / 36卷 / 03期

关键词：

Nuclear Magnetic Resonance - Polymers--Spectroscopic Analysis - Spectroscopy;

D O I：

10.1002/app.1988.070360318

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel class of bismaleimides, biscitraconimides, and bisdichloromaleimides chain-extended by pyromellitimide was prepared and characterized by infrared and proton nuclear magnetic resonance spectroscopy. These polymer precursors were prepared by reacting maleic/citraconic/dichloromaleic anhydride (1 mol) with an equimolar amount of a diamine and subsequently with pyromellitic dianhydride (0.5 mol). The tetraamic acid formed was cyclodehydrated by chemical or thermal means. The curing behavior of polymer precursors was investigated by differential thermal analysis. The curing temperature of monomers fluctuated between 209 and 318°C. Dynamic thermogravimetric analysis of the cured aromatic resins showed that they were approximately stable up to 370°C both in nitrogen and air.

引用

页码：691 / 702

页数：12

共 21 条

[1]

ARNOLD C, 1979, MACROMOL REV, V14, P265

[2]

Bargain M., 1971, Cross-linked resins, Patent No. [US 3562223, 3562223]

[3]

BOVEY FA, 1969, NUCLEAR MAGNETIC RES, P58

[4]

EHLERS GFL, 1974, AFMLTR74177

[5]

Fundschober F., 1968, U.S. Patent, Patent No. [3,380,964, 3380964]

[6]

GRUNDSCHOBER F, 1970, Patent No. 3533966

[7]

HAGNAUER GL, 1976, J APPL POLYM SCI, V20, P3073, DOI 10.1002/app.1976.070201113

[8] INFRARED SPECTROSCOPIC DETERMINATION OF KINETIC DATA OF POLYMERIZATION OF ALIPHATIC BISMALEIMIDES [J].

HUMMEL, DO ;

HEINEN, KU ;

STENZENB.H ;

SIESLER, H .

JOURNAL OF APPLIED POLYMER SCIENCE, 1974, 18 (07) :2015-2024

[9] AROMATIC POLYAMIDES .5. SUBSTITUENT EFFECT ON THERMAL-PROPERTIES [J].

KHANNA, YP ;

PEARCE, EM .

JOURNAL OF APPLIED POLYMER SCIENCE, 1982, 27 (06) :2053-2064

[10]

Kovacic P., 1957, U. S. Pat., Patent No. [2818405A, 2818405]

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