NMR-STUDIES OF THE GOLD(I)-CATALYZED ASYMMETRIC ALDOL REACTION OF ISOCYANOACETATE

被引：42

作者：

SAWAMURA, M

ITO, Y

HAYASHI, T

机构：

[1] KYOTO UNIV, FAC ENGN, DEPT SYNTHET CHEM, KYOTO 606, JAPAN

[2] HOKKAIDO UNIV, CATALYSIS RES CTR, SAPPORO, HOKKAIDO 060, JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(00)94683-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A ferrocenylphosphine-silver-isocyanoacetate complex was investigated as a model compound for catalytic species in gold-catalyzed aldol reaction. 1H{1H} NOE studies of the silver complex indicated that terminal amino group of pendant side chain of the ferrocenylphosphine ligand is located close to active hydrogens of isocyanoacetate coordinated. © 1990.

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页码：2723 / 2726

页数：4

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