PREPARATION AND REACTIONS OF ALLENIC ZIRCONIUM SPECIES FROM PROPARGYLIC ETHER DERIVATIVES

被引：41

作者：

ITO, H ^{[1
]}

NAKAMURA, T ^{[1
]}

TAGUCHI, T ^{[1
]}

HANZAWA, Y ^{[1
]}

机构：

[1] TOKYO COLL PHARM,1432-1 HORINOUCHI,HACHIOJI,TOKYO 19203,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 26期

关键词：

ZIRCONOCENE; ZIRCONACYCLOPROPENE; PROPARGYLIC ETHER DERIVATIVES; ALLENIC ZIRCONIUM SPECIES;

D O I：

10.1016/0040-4039(92)80020-K

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The generation of allenic zirconium intermediates by treating propargylic ether derivatives with ''Cp2Zr'' and their reactions with aldehydes in the presence of borontrifluoride etherate yield anti-beta-acetylenic alcohols along with alpha-allenic alcohols.

引用

页码：3769 / 3772

页数：4

共 15 条

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