SYNTHESIS AND CYCLOADDITION OF 2-(DIALKOXYBORYL)-1,3-BUTADIENE

被引：31

作者：

KAMABUCHI, A ^{[1
]}

MIYAURA, N ^{[1
]}

SUZUKI, A ^{[1
]}

机构：

[1] HOKKAIDO UNIV,FAC ENGN,DEPT APPL CHEM,SAPPORO,HOKKAIDO 060,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 30期

关键词：

D O I：

10.1016/S0040-4039(00)74099-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A two-step procedure for the synthesis of a pinacol ester of (1,3-butadien-2-yl)boronic acid 2 from 1,4-dichloro-2-butyne is reported. The boronate 2 is found to be an extremely reactive diene for the Diels-Alder reaction to produce functionalized cyclic 1-alkenylboronates in high yields.

引用

页码：4827 / 4828

页数：2

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