END GROUP MODIFICATION OF PULLULAN

被引：12

作者：

BRUNEEL, D ^{[1
]}

SCHACHT, E ^{[1
]}

机构：

[1] STATE UNIV GHENT, DEPT ORGAN CHEM, BIOMAT & POLYMER RES GRP, B-9000 GHENT, BELGIUM

来源：

POLYMER | 1995年 / 36卷 / 01期

关键词：

PULLULAN; REDUCTIVE AMINATION; END GROUP;

D O I：

10.1016/0032-3861(95)90688-X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Pullulan was selectively functionalized at its reducing terminus via reductive amination of the terminal aldehyde with 2-(4-nitrophenyl)ethylamine. The nitro group serves as a precursor for an amino group which can be converted into a reactive isothiocyanate group. The latter can be coupled with amines.

引用

页码：169 / 172

页数：4

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