Oxidation by transition metal complexes. II. Oxidation of styrenes catalyzed by rhodium compounds

被引：51

作者：

Takao, Kiyotorni ^{[1
]}

Wayaku, Masarni ^{[1
]}

Fuilwara, Yuzo ^{[1
]}

Imanaka, Toshinobu ^{[1
]}

Teranishi, Shiichiro ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn Sci, Dept Chem Engn, Toyonaka, Osaka, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1970年 / 43卷 / 12期

关键词：

D O I：

10.1246/bcsj.43.3898

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic activities of chlorotris(triphenylphosphine)rhodium(I) and rhodium(III) chloride for the oxidation of olefins have been studied. It has been found that the complex and RhCl3 can cause catalytically the oxidation of aliphatic olefins such as styrene, alpha-methylstyrene or beta-methylstyrene to produce carbonyl compounds under oxygen atmosphere. A remarkable solvent effect was observed in the reaction.

引用

页码：3898 / 3900

页数：3

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