ISOLATION OF CONFORMATIONAL ISOMERS OF ALPHA-IONONES AND BETA-IONONES BY INCLUSION COMPLEX-FORMATION

被引:21
作者
TODA, F [1 ]
TANAKA, K [1 ]
FUJIWARA, T [1 ]
机构
[1] SHIMANE UNIV,FAC SCI,DEPT CHEM,MATSUE,SHIMANE 690,JAPAN
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 06期
关键词
D O I
10.1002/anie.199006621
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Complexation with 1 as host molecule allows isolation of S‐trans‐β‐ionone 2a, whereas 3 selectively forms an inclusion compound with the S‐cis‐isomer 2b. The conformation of the complexed isomers were respectively determined by an X‐ray structure analysis and spectroscopically. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany
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页码:662 / 664
页数:3
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