CHIRAL COMPLEXES OF NI(II), CU(II), AND CU(I) AS REAGENTS, CATALYSTS AND RECEPTORS FOR ASYMMETRIC-SYNTHESIS AND CHIRAL RECOGNITION OF AMINO-ACIDS

被引：99

作者：

BELOKON, YN

机构：

[1] Nesmevanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow

来源：

PURE AND APPLIED CHEMISTRY | 1992年 / 64卷 / 12期

关键词：

D O I：

10.1351/pac199264121917

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New reagents and catalysts for the asymmetric syntheses of amino acids were developed. Among the reactions which have been studied are alkylation, carbonyl and C=C bond addition reactions of a chiral 'glycine equivalent'. Chiral phase-transfer and hydrolysis catalysts, based on chiral Cu(II) complexes, have been used to promote asymmetric alkylation of an achiral 'glycine equivalent' and hydrolysis of racemic azlactones. Transition metal based new type of chiral receptors for amino acid anions was developed.

引用

页码：1917 / 1924

页数：8

共 26 条

[1]

Barret G.C., 1985, CHEM BIOCHEM AMINO

[2] GENERAL-METHOD FOR THE ASYMMETRIC-SYNTHESIS OF ANTIDIASTEREOISOMERS OF BETA-SUBSTITUTED L-2-AMINOBUTANOIC ACIDS VIA CHIRAL NICKEL(II) SCHIFFS BASE COMPLEXES OF DEHYDROAMINOBUTANOIC ACID - X-RAY CRYSTAL AND MOLECULAR-STRUCTURE OF THE NICKEL(II) COMPLEX OF THE SCHIFFS BASE FROM [(BENZYLPROLYL)AMINO]BENZOPHENONE AND DEHYDROAMINOBUTANOIC ACID [J].

BELOKON, YN ;

SAGYAN, AS ;

DJAMGARYAN, SA ;

BAKHMUTOV, VI ;

VITT, SV ;

BATSANOV, AS ;

STRUCHKOV, YT ;

BELIKOV, VM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1990, (08) :2301-2310

[3] SYNTHESIS OF A CHIRAL NICKEL(II) COMPLEX OF AN ELECTROPHILIC GLYCINATE, AND ITS USE FOR ASYMMETRIC PREPARATION OF ALPHA-AMINO-ACIDS [J].

BELOKON, YN ;

POPKOV, AN ;

CHERNOGLAZOVA, NI ;

SAPOROVSKAYA, MB ;

BAKHMUTOV, VI ;

BELIKOV, VM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (19) :1336-1338

[4] GENERAL-METHOD FOR THE ASYMMETRIC-SYNTHESIS OF ALPHA-AMINO-ACIDS VIA ALKYLATION OF THE CHIRAL NICKEL(II) SCHIFF-BASE COMPLEXES OF GLYCINE AND ALANINE [J].

BELOKON, YN ;

BAKHMUTOV, VI ;

CHERNOGLAZOVA, NI ;

KOCHETKOV, KA ;

VITT, SV ;

GARBALINSKAYA, NS ;

BELIKOV, VM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (02) :305-312

[5] ASYMMETRIC-SYNTHESIS OF BETA-SUBSTITUTED ALPHA-AMINO-ACIDS VIA A CHIRAL NI-II COMPLEX OF DEHYDROALANINE [J].

BELOKON, YN ;

SAGYAN, AS ;

DJAMGARYAN, SM ;

BAKHMUTOV, VI ;

BELIKOV, VM .

TETRAHEDRON, 1988, 44 (17) :5507-5514

[6] GENERAL-METHOD OF DIASTEREOSELECTIVE AND ENANTIOSELECTIVE SYNTHESIS OF BETA-HYDROXY-ALPHA-AMINO ACIDS BY CONDENSATION OF ALDEHYDES AND KETONES WITH GLYCINE [J].

BELOKON, YN ;

BULYCHEV, AG ;

VITT, SV ;

STRUCHKOV, YT ;

BATSANOV, AS ;

TIMOFEEVA, TV ;

TSYRYAPKIN, VA ;

RYZHOV, MG ;

LYSOVA, LA ;

BAKHMUTOV, VI ;

BELIKOV, VM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (14) :4252-4259

[7] SYNTHESIS OF ENANTIOMERICALLY AND DIASTEREOISOMERICALLY PURE SUBSTITUTED PROLINES VIA CONDENSATION OF GLYCINE WITH OLEFINS ACTIVATED BY A CARBONYL GROUP [J].

BELOKON, YN ;

BULYCHEV, AG ;

PAVLOV, VA ;

FEDOROVA, EB ;

TSYRYAPKIN, VA ;

BAKHMUTOV, VA ;

BELIKOV, VM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (08) :2075-2083

[8] SYNTHESIS OF ENANTIO-ISOMERICALLY AND DIASTEREO-ISOMERICALLY PURE BETA-SUBSTITUTED AND GAMMA-SUBSTITUTED GLUTAMIC ACIDS VIA GLYCINE CONDENSATION WITH ACTIVATED OLEFINS [J].

BELOKON, YN ;

BULYCHEV, AG ;

RYZHOV, MG ;

VITT, SV ;

BATSANOV, AS ;

STRUCHKOV, YT ;

BAKHMUTOV, VI ;

BELIKOV, VM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (11) :1865-1872

[9] CHIRAL COMPLEXES OF COPPER(II), CONTAINING POLYETHER PODANDS AND A QUATERNARY AMMONIUM GROUP, AS POTENTIAL RECEPTORS AND CARRIERS OF ALPHA-AMINO-ACID ANIONS [J].

BELOKON, YN ;

PRITULA, LK ;

TARAROV, VI ;

BAKHMUTOV, VI ;

GUSEV, DG ;

SAPOROVSKAYA, MB ;

BELIKOV, VM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (06) :1873-1877

[10] SYNTHESIS OF CHIRAL ATROPOISOMERIC SQUARE-PLANAR NICKEL(II) AND COPPER(II) COMPLEXES FORMED BY MACROCYCLIC LIGANDS CONTAINING PENDANT POLYETHER GROUPS AND A QUATERNARY AMMONIUM GROUP [J].

BELOKON, YN ;

PRITULA, LK ;

TARAROV, VI ;

BAKHMUTOV, VI ;

STRUCHKOV, YT ;

TIMOFEEVA, TV ;

BELIKOV, VM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (06) :1867-1872

← 1 2 3 →