SYNTHESIS AND CRYSTAL-STRUCTURE OF A DINUCLEAR YTTRIUM(III)-(LANTHANIDE(III)-) COPPER(II) COMPLEX WITH AN UNUSUAL 2-METHYL-2,4,6-TRIS(TRIFLUOROMETHYL)-1,3-DIOXANE-4,6-DIOLATO LIGAND

被引:52
作者
WANG, SN
PANG, Z
SMITH, KDL
机构
关键词
D O I
10.1021/ic00075a004
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A dinuclear Ln(III)-Cu(II) complex with an unusual 2-methyl-2,4,6-tris(trifluoromethyl)-1,3-dioxane-4,6-diolato ligand has been synthesized and characterized structurally. The 1,3-dioxane-4,6-diolato ligand is the product of cycloaddition of 1,1,1-trifluoro-2,2-propanediol to a hexafluoroacetylacetonato ligand promoted by the metal complex.
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页码:4992 / 4993
页数:2
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