NOVEL CYCLIZATIONS INVOLVING VINYL SULFONES - STEREOSELECTIVE CONSTRUCTION OF PERHYDROAZULENES AND TRANS-HYDRINDANES

被引：13

作者：

JONES, DN

MAYBURY, MWJ

SWALLOW, S

TOMKINSON, NCO

机构：

[1] Department of Chemistry, The University, Sheffield

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(00)61383-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Anionic species formed by treatment of vinyl sulfones with hydridoaluminates were trapped intramolecularly by esters to provide six- and seven-membered cyclic ketosulfones, exemplified by the stereoselective construction of trans-hydrindanes and of perhydroazulenes. This led to formal syntheses of confertin and damsinic acid.

引用

页码：8553 / 8556

页数：4

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