SILICON CARBON UNSATURATED-COMPOUNDS .30. THERMAL-ISOMERIZATION OF 1-MESITYL-3-PHENYL-1,2-BIS(TRIMETHYLSILYL)-1-SILACYCLOPROPENE AND 2-MESITYL-2-(PHENYLETHYNYL)HEXAMETHYLTRISILANE

被引：15

作者：

ISHIKAWA, M

YUZURIHA, Y

HORIO, T

KUNAI, A

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Hiroshima University, Higashi-Hiroshima

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 402卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)83073-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermolysis of 1-mesityl-3-phenyl-1,2-bis(trimethylsilyl)-1-silacyclopropene at 280-degrees-C afforded 1-mesityl-3,3-dimethyl-4-phenyl-5-(trimethylsilyl)-1, 3-disilacyclo-4-penetene and 1-mesityl-1,3-bis(trimethylsilyl)-1-silaindene. Similar thermolysis of 2-mesityl-2-(phenylethynyl)hexamethyltrisilane produced the same products.

引用

页码：C20 / C22

页数：3

共 6 条

[1] RADICAL REARRANGEMENTS IN THE PYROLYSIS OF ALLYLDISILANES [J].