ORGANOMETALLIC SYNTHESIS VIA SURFACE-MEDIATED REACTIONS - HIGH-YIELD ROUTE TO HOS3(CO)10(OH)

被引：25

作者：

DOSSI, C ^{[1
]}

FUSI, A ^{[1
]}

PIZZOTTI, M ^{[1
]}

PSARO, R ^{[1
]}

机构：

[1] UNIV MILAN,CTR CNR,I-20133 MILAN,ITALY

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 07期

关键词：

D O I：

10.1021/om00157a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The silica-anchored hydrido cluster HOs3-(CO)10(OSi⪪) is easily prepared from physisorbed Os3(CO)12. Chemical displacement from the surface with HF leads to the isolation of pure HOs3(CO)10(OH). This approach is far simpler and gives much higher yields than the conventional syntheses in solution. © 1990, American Chemical Society. All rights reserved.

引用

页码：1994 / 1995

页数：2

共 10 条

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