ON THE VALIDITY OF PARTITIONING TECHNIQUES FOR MOLECULAR INFRARED-MULTIPHOTON EXCITATION

被引：6

作者：

JOLICARD, G

GROSJEAN, A

机构：

[1] Laboratoire de Physique Moléculaire, Université de Franche-Comté, CNRS URA 772, La Bouloie

来源：

JOURNAL OF CHEMICAL PHYSICS | 1991年 / 95卷 / 03期

关键词：

D O I：

10.1063/1.461041

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A wave operator treatment of the molecular infrared-multiphoton excitation is presented. The Bloch's wave operator concept is used as a tool to define a model space around the initial state and to build inside this space the effective Hamiltonian which drives the dynamics. Simple applications made with a rotator coupled to an intense laser field demonstrate the validity of this formulation.

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页码：1920 / 1927

页数：8

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