BIOGENETIC SYNTHESIS OF AN ANDROCYMBINE-TYPE COMPOUND

被引：15

作者：

KAMETANI, T

FUKUMOTO, K

KOIZUMI, M

KOZUKA, A

机构：

[1] Pharmaceutical Institute, School of Medicine, Tohoku University, Sendai, No. 85, Kitayobancho

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 09期

关键词：

D O I：

10.1039/j39690001295

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phenolic oxidative coupling of 1,2,3,4-tetrahydro-7-hydroxy-1-(3-hydroxy-4-methoxyphenethyl)-6-methoxy-2- methylisoquinoline (VIII) with potassium ferricyanide afforded a homomorphinandienone-type compound (IX). which was methylated with diazomethane to give demethyl-O-methylandrocymbine (X), identical with an authentic sample obtained by a modified Pschorr reaction.

引用

页码：1295 / &

共 27 条

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