CHEMISTRY OF ALIPHATIC DISULFIDES .16. STUDIES ON ALKOXIDE CLEAVAGE OF 1,6-DIPHENYL-3,4-DITHIA-1,6-HEXANEDIONE

被引：10

作者：

HISKEY, RG

DENNIS, AJ

机构：

[1] Venable Chemical Laboratory, University of North Carolina, Chapel Hill, North Carolina

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1968年 / 33卷 / 02期

关键词：

D O I：

10.1021/jo01266a019

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of 1,6-diphenyl-3,4-dithia-1,6-hexanedione (I) with 2 equiv ofpotassium ethoxide provides dipotassio-1,4-diphenyl-1,4-butaned:one 2,3-dimercaptide (VI) and potass o-1,4-diphenyl-2-butene-1,4-dione 2-mercaptide (VII) as the major products. A mechanism for the formation of VII isproposed to involveVI as the precursor. © 1968, American Chemical Society. All rights reserved.

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页码：563 / &

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