METAL BETAINE INTERACTIONS .6. CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAKIS(BETAINE)COPPER(II) NITRATE, [CU(ME3NCH2COO)4](NO3)2

被引：44

作者：

CHEN, XM ^{[1
]}

MAK, TCW ^{[1
]}

机构：

[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,HONG KONG

来源：

POLYHEDRON | 1991年 / 10卷 / 02期

关键词：

D O I：

10.1016/S0277-5387(00)81600-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal and molecular structure of [Cu(BET)4]. (NO3)2 (BET = Me3 N+CH2COO-) has been established by X-ray crystallography. The complex consists of discrete [Cu(BET)4]2+ and nitrate anions, with the copper(II) atom eight-coordinated by four short Cu-O(carboxy) bonds [1.948(3) angstrom] and four long Cu-O(carboxy) bonds [2.833(4) angstrom] in a distorted dodecahedral 4BAR2m (D(2d)) environment.

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页码：273 / 276

页数：4

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